Tourmaline is a crystal boron silicate mineral compounded with elements such as aluminium, iron, magnesium, sodium, lithium, or potassium. Tourmaline is classified as a semi-precious stone and the gem comes in a wide variety of colors. The name comes from the Sinhalese word "Thuramali" or "Thoramalli" which applied to different gemstones found in Sri Lanka.
Brightly colored Sri Lankan gem tourmalines were brought to Europe in great quantities by the Dutch East India Company to satisfy a demand for curiosities and gems. At the time it was not realised that schorl and tourmaline were the same mineral.
Chemical Composition:
A complex silicate - WX
3 Y
6 B
3 Si
6 O
27 (O,OH,F)
4 . In elbaite tourmaline X = mainly Li & Al, W = Na, Y = Al. Mg, Fe, Ca, etc., replace isomorphously.
Classification / Type:
The tourmaline group is made up of a number of
different members. Of gem interest are the Elbaite tourmalines which are
found in many colors; other related varieties such as dravite
tourmaline (brown), schorl tourmaline (black), indicolite tourmaline
(blue), rubellite tourmaline (red), liddicoatite tourmaline etc. are
also being used as gemstones. Since the distinctions are of a purely
chemical nature, all these are considered as a single species -
tourmaline.
Colors / Varieties:
All colors. / Parti-colored and chatoyant.
Transparency:
Transparent to Opaque.
Crystal System / Forms:
Trigonal System / Prismatic habit showing
hemimorphism; deep vertical striations / grooves on the prism face are
characteristic.
Specific Gravity:
Pink tourmaline: 3.03
Red and pale green tourmaline: 3.05
Brown tourmaline: 3.06
Dark Green tourmaline: 3.08
Blue, yellow tourmaline: 3.10
Black tourmaline: more than 3.15
Cleavage / Fracture:
None / Conchoidal
Optic Character:
Anisotropic,
D.R. ; Uniaxial negative.
Refractive Index / Birefringence:
1.624 - 1.644 / 0.020. Range: 1.618 - 1.650
Pleochroism:
Distinct dichroism with strong absorption along c-axis. Varies with color.
Magnification:
Liquid inclusions, trichites (fine liquid
capillaries or tubes), highly reflecting inclusions, phase and crystal
inclusions.
U.V. Fluorescence:
Weak to inert in longwave and varies with colors in shortwave.
Spectrum:
Varies as per composition.
Cause of Color:
Red and pink tourmaline: Manganese (some pink - titanium)
Blue tourmaline: Iron
Green tourmaline: Iron / Chromium / Vanadium
Purple tourmaline: Iron and Manganese
Treatment (Enhancement):
Colorless impregnation: oil / resin to improve clarity
Heat treatment: lighten dark colors
Irradiation: darkens colors e.g. darker pink
Specific Tests:
Pyroelectric: Develops an electrical charge when heated.
Piezoelectric: Develops and electrical charge when pressure is
applied parallel to the c-axis direction. This is made use of in depth
recording apparatus in deep sea explorations.
Simulants (with separation tests):
Aquamarine (
R.I. ,
S.G. , inclusions), Andalusite (optic figure, pleochroism, birefringence), Apatite (hardness, birefringence, spectrum), Danburite (optic figure,
R.I. , birefringence, pleochroism), Iolite (pleochroism, optic figure,
R.I. ,
S.G. ), Beryl (
R.I. , birefringence,
S.G. , pleochroism), Citrine (
R.I. ,
S.G. , pleochroism), Tsavorite Garnet (optic character), Chrome Diopside (optic figure,
R.I. , birefringence,
S.G. ), Red Spinel (optic character), etc.
Geological Occurrence:
In crystalline schists, in granites, pegmatite.
Sources:
Brazil (from Paraiba known as Paraiba tourmaline),
South-west Africa, Russia (Ural Mountains), Zambia, Madagascar,
Tanzania, Sri Lanka, Kenya, Pakistan, Myanmar, etc.
Cuts & Uses:
Faceted cuts, cabochon, beads in jewelry, carvings.