Quartz is the second-most-abundant mineral in the Earth's continental crust, after feldspar. It is made up of a continuous framework of SiO4 silicon-oxygen tetrahedra, with each oxygen being shared between two tetrahedra, giving an overall formula SiO2. There are many different varieties of quartz, several of which are semi-precious gemstones. Throughout the world, varieties of quartz have been since antiquity the most commonly used minerals in the making of jewelry and hardstone carvings.
The quartz group includes a number of different species / varieties. There are two categories crystalline quartz and cryptocrystalline quartz (chalcedony).
Chemical Composition:
Silica (Silicon Dioxide) SiO
2
Colors / Varieties:
Colorless: Rock Crystal
Violet: Amethyst
Yellow, Golden: Citrine
Brown, Grey: Smoky Quartz (Morion)
Pink: Rose Quartz
Green: Praseolite
Rock Crystal with irridescent cracks: Iris Quartz
Red Quartz: Rare Variety
Blue, green (aventurescent): Aventurine Quartz
Quartz Cat's Eye
Star Quartz (Six Ray)
Parti Color Quartz: Ametrine
Sagenitic Quartz (Tourmalinated / Rutilated)
Tiger's Eye / Hawk's Eye
Milky Quartz
Quartzite
Crystal System / Forms:
Trigonal System
Prismatic with pyramidal terminations (rhombohedron, trapezohedron, trigonal, pyramid)
Horizontal striations on the prism face, rhomb shaped on rhombohedral face, 'V' shaped markings in twinned crystals.
Most quartz is commonly twinned.
Types of twinning include Dauphine, Brazil and Japan law twinning.
Exhibits both contact and interpenetrant twinning.
Specific Gravity:
2.63 - 2.68
Cleavage / Fracture:
No distinct cleavage / conchoidal to uneven fracture.
Optic Character:
Anisotropic,
D.R. ;
Uniaxial positive. May exhibit a bull's eye optic figure (quartz
rotates the plane of polarisation parallel to the c-axis).
Refractive Index / Birefringence:
1.544 - 1.553 / 0.009. Range: 1.535 - 1.560
Pleochroism:
Dichroism - weak to moderate.
Magnification:
Liquid and two phase, color zoning, negative
crystals, zebra-stripe finger prints (structural), crystal inclusions,
green fuchsite mica flakes / platelets in aventurine quartz, rutile / tourmaline needles in sagenitic quartz. Brazil law twinning is seen in natural quartz.
U.V. Fluorescence:
Variable.
Spectrum:
Green aventurine: bands at 682
nm , 649
nm
Cause of Color:
Rose Quartz: Charge transfer reaction (Ti
4+ and Fe
2+ ) as a result of irradiation.
Treatment (Enhancement):
Bleaching: lightening of tiger's eye.
Coating: all colors, thin film of gold on colorless will give a blue color (aqua aura).
Colorless impregnation: with oil or resin to improve clarity.
Colored impregnation (dyeing): all colors, quartzite
Heat Treatment:
Deep pink to light pink
Crackling to produce iris quartz
Irradiation:
Light pink to deep pink
Specific Tests:
Piezoelectric: develops an electric charge when pressure is applied.
Pyroelectricity: develops an electrical charge when heated.
Diasterism in star variety (star visible in reflected and transmitted light).
Synthesis:
Hydrothermal process:
Colors - colorless, pink, blue, green, etc.
Identification: type of twinning, seed plate, breadcrumb inclusions, Raman / infra-red spectroscopy.
Geological Occurrence:
Very widespread, in pegmatite.
Sources:
Brazil, India, South Africa, Namibia, Madagascar, Zambia, Sri Lanka.
Cuts & Uses:
Facetted cuts, cabochon, carvings, beads, etc.